Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days). 相似文献
The thermal structure of Archean and Proterozoic lithospheric terranes in southern Africa during the Mesozoic was evaluated by thermobarometry of mantle peridotite xenoliths erupted in alkaline magmas between 180 and 60 Ma. For cratonic xenoliths, the presence of a 150–200 °C isobaric temperature range at 5–6 GPa confirms original interpretations of a conductive geotherm, which is perturbed at depth, and therefore does not record steady state lithospheric mantle structure.
Xenoliths from both Archean and Proterozoic terranes record conductive limb temperatures characteristic of a “cratonic” geotherm (40 mW m−2), indicating cooling of Proterozoic mantle following the last major tectonothermal event in the region at 1 Ga and the probability of thick off-craton lithosphere capable of hosting diamond. This inference is supported by U–Pb thermochronology of lower crustal xenoliths [Schmitz and Bowring, 2003. Contrib. Mineral. Petrol. 144, 592–618].
The entire region then suffered a protracted regional heating event in the Mesozoic, affecting both mantle and lower crust. In the mantle, the event is recorded at 150 Ma to the southeast of the craton, propagating to the west by 108–74 Ma, the craton interior by 85–90 Ma and the far southwest and northwest by 65–70 Ma. The heating penetrated to shallower levels in the off-craton areas than on the craton, and is more apparent on the southern margin of the craton than in its western interior. The focus and spatial progression mimic inferred patterns of plume activity and supercontinent breakup 30–100 Ma earlier and are probably connected.
Contrasting thermal profiles from Archean and Proterozoic mantle result from penetration to shallower levels of the Proterozoic lithosphere by heat transporting magmas. Extent of penetration is related not to original lithospheric thickness, but to its more fertile character and the presence of structurally weak zones of old tectonism. The present day distribution of surface heat flow in southern Africa is related to this dynamic event and is not a direct reflection of the pre-existing lithospheric architecture. 相似文献
In the metamorphic cores of many orogenic belts, large macroscopic folds in compositional layering also appear to fold one or more pervasive matrix foliations. The latter geometry suggests the folds formed relatively late in the tectonic history, after foliation development. However, microstructural analysis of four examples of such folds suggests this is not the case. The folds formed relatively early in the orogenic history and are the end product of multiple, near orthogonal, overprinting bulk shortening events. Once large macroscopic folds initiate, they may tighten further during successive periods of sub-parallel shortening, folding or reactivation of foliations that develop during intervening periods of near orthogonal shortening. Reactivation of the compositional layering defining the fold limbs causes foliation to be rotated into parallelism with the limbs.Multiple periods of porphyroblast growth accompanied the multiple phases of deformation that postdated the initial development of these folds. Some of these phases of deformation were attended by the development of large numbers of same asymmetry spiral-shaped inclusion trails in porphyroblasts on one limb of the fold and not the other, or larger numbers of opposite asymmetry spirals on the other limb, or similar numbers of the same asymmetry spirals on both limbs. Significantly, the largest disparity in numbers from limb to limb occurred for the first of these cases. For all four regional folds examined, the structural relationships that accompanied these large disparities were identical. In each case the shear sense operating on steeply dipping foliations was opposite to that required to originally develop the fold. Reactivation of the folded compositional layering was not possible for this shear sense. This favoured the development of sites of approximately coaxial shortening early during the deformation history, enhancing microfracture and promoting the growth of porphyroblasts on this limb in comparision to the other. These distributions of inclusion trail geometries from limb to limb cannot be explained by porphyroblast rotation, or folding of pre-existing rotated porphyroblasts within a shear zone, but can be explained by development of the inclusion trails synchronous with successive sub-vertical and sub-horizontal foliations. 相似文献